Supernatural : Book of the Damned (2005)
Directed by P.J. Pesce
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Synopsis
Charlie calls Sam and Dean and tells them she found the Book of the Dead that could help remove the Mark of Cain. Unfortunately, a man who claims the book belongs to his family shoots her. Meanwhile, Castiel and Metatron take a road trip to find Castiel's grace, but the journey doesn't go as planned.