Spiderman: The Ultimate Villain Showdown (2002)

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Released just in time to capitalize on Sam Raimi's 2002 big-screen treatment of the famed web-slinger, Spiderman: The Ultimate Villain Showdown collects a handful of episodes from the animated series that aired in the mid '90s. These episodes show the creation of Spidey's arch-villains Dr. Octopus, Green Goblin, and Kingpin. Fans of the character should be interested in this Buena Vista release.